(2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate
نویسندگان
چکیده
In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra-hedrally coordinated by a bidentate 2,2'-bipyridine ligand and two PPh(3) ligands. The Cu-N and Cu-P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra-hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring-ring C-C bond. The nitrate anion and the water and chloro-form mol-ecules of solvation are disordered. In the crystal structure, there are O(water)-H⋯O(nitrate), C-H⋯O(water) and C-H⋯O(nitrate) hydrogen bonds.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)bis(N-ethyl-N-phenyldithiocarbamato-κ2 S,S′)cadmium(II) chloroform solvate
In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa-hedral geometry. Chelation is isobidentate for one dithio-carbamate ligand and anisobidentate for the other. The chloroform solvent mol-ecule is disordered over two positions of equal occupancy.
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